应用能谱扫描电镜与X射线衍射等分析技术研究西藏扎西康铅锌矿中伴生元素锰的赋存状态     

徐国栋  王冠  程江  董随亮 《岩矿测试》2014,33(6):808-812

西藏扎西康铅锌多金属矿床是我国首次发现的喷流沉积-热泉水改造型锰铁锑铅锌银矿床,已有研究表明矿床中除了铅锌矿还伴生有银、锑、铜、硫、锰、砷等多种元素。本文在化学多元素分析和光学显微镜镜下鉴定的基础上,结合能谱扫描电子显微镜和X射线衍射分析等手段对扎西康铅锌矿中伴生组分Mn的含量、矿物种类、嵌布和包裹等特性进行了研究。分析结果表明,原生矿石的主要成矿元素Pb和Zn的含量分别为6.00%和4.00%,伴生元素Mn的含量平均达到4.36%;原生矿石中的主要矿物为方铅矿、闪锌矿,其次为黄铁矿、毒砂和菱锰矿等。原生矿石中伴生元素Mn主要以独立的菱锰矿和铁菱锰矿形式存在,与闪锌矿和方铅矿密切共生,是成矿早期重要的载矿矿物,嵌布在石英、黄铁矿、闪锌矿和毒砂的粒间、边部及空隙间,其次以类质同象形式赋存于菱铁矿和菱锌矿中。进一步对扎西康铅锌矿选冶产物中的伴生元素Mn的含量和赋存状态进行研究,研究表明Mn具有较高的综合利用价值,在原生矿石、铅精矿、锌精矿和尾矿中的质量分数分别为4.36%、0.51%、0.95%和5.36%,显示Mn很少一部分进入铅精矿和锌精矿,而绝大部分进入尾矿;Mn在尾矿中仍主要以菱锰矿形式存在,存在形式与原生矿石相比未发生改变,可通过强磁选工艺从铅锌尾矿中综合回收利用Mn。  相似文献   

熔融制样波长色散X射线荧光光谱法测定白云石中钙镁硅铁铝   总被引：4，自引：3，他引：1  

褚宁  李卫刚  蒋晓光  张彦甫  毕孝瑞 《岩矿测试》2014,33(6):834-838

白云石属碳酸盐矿物,应用熔融制样X射线荧光光谱法测定其中主次量组分钙、镁、硅、铁、铝时,由于白云石灼烧减量大,在试料片制备过程中,如果以干基试料制备试料片,除灼烧减量外还有少量其他组分被分解出的大量CO₂带走,导致试料损失,测定结果偏低;如果以灼烧基试料制备试料片,由于灼烧后的试料极易吸收空气中的水分和CO₂,同样使测定结果偏低。基于质量守恒原理,本文直接以灼烧减量测量后的灼烧基试料质量作为试料量(即灼烧减量测定所称量的干基试料量扣除灼烧减量的量),以四硼酸锂为熔剂,5%碘化铵溶液为脱模剂,试料与熔剂的稀释比为1:10,于1050℃熔融15 min以上制备的试料片透彻、玻璃化程度高。以白云石标准物质和标准样品作为标准试料,制作各组分的标准曲线的相关系数在0.9940~0.9994之间;方法检出限为0.011%~0.48%;标准物质和标准样品的测定值与认定值基本一致,各组分的相对标准偏差(RSD,n=11)在0.5%~1.7%之间,方法具有较好的重现性。本方法以1050℃灼烧后的试样作为试料制备XRF分析样片,最大限度地降低了灼烧减量因素(空气中的水分和CO₂)对测定结果的影响,适用于白云石及其煅烧物中钙、镁、硅、铁、铝等组分的同时测定。  相似文献   

小型激光天文动力学空间计划概念   总被引：1，自引：0，他引：1  

倪维斗  朱进  武向平  褚桂柏  杨彬  高健  关敏  汤健仁  周翊  张中豪  黄天衣  曲钦岳  易照华  李广宇  陶金河  吴岸明  罗俊  叶贤基  周泽兵  熊耀恒  毕少兰  须重明  吴雪君  唐孟希  包芸  李芳昱  黄珹  杨福民  叶叔华  张书练  张元仲  聂玉昕  陈光  Joergen Christensen-Dalsgaard  Hansjoerg Dittus  Yasunori Fujii  Claus Laemmerzahl  Jean Francois Mangin  Achim Peters  Albrecht Ruediger  Etienne Samain  Stephan Schiller 《天文研究与技术》2002,(3):123-136

小型激光天文动力学空间计划是 :使用在太阳轨道上无拖曳航天器和地面站以激光干涉和脉冲测距的方法 ,精确地探讨天文动力学 ,检测相对论与时空基本定律 ,改进探测引力波的灵敏度以及更准确地测定太阳、行星和小行星的参数。 1 969年开始的月球激光 (反射 )测距 ,对地球物理、参考坐标的选定、相对论的检验均有重要的贡献。 3 0年来 ,激光技术的长足进步 ,使现在正是适合于开始进行研究空间有源 (主动 )测距和光波空间通讯的时候。激光天文动力学的兴起是必然的趋势 ,其精确度将比现在提高 3到 6个数量级 ,将是天文动力学革命性的发展。小型激光天文动力学空间计划可以起到带头作用。它的关键技术有三 ,即 :弱光锁相、极精确无拖曳航天和高衰减日冕仪。弱光锁相已有长足的进步。对高衰减日冕仪的研究 ,也有了初步的方案。LISA空间计划将于 2 0 0 6年 8月发射SMART -2 ,研究测试极精确无拖曳航天。小型激光天文动力学空间计划的关键技术已日趋成熟。在第一届国际激光天文动力学研讨会 ( 2 0 0 1 ,9.1 3 -2 3 )中介绍了各相关学科背景及前沿研究 ,讨论了激光天文动力学空间计划科学目标及相关技术 ,并召开了两次小型激光天文动力学空间计划预研究筹备会 ,建立了和欧洲的合作关系。会后着手进行此项对基础  相似文献   

激光天文动力学弱光锁相的研究     

廖安琪  倪维斗  施宙聪 《天文研究与技术》2002,331(3):88-100

近年来激光物理与应用的进展促成了激光天文动力学空间任务概念的提出。在激光天文动力学任务概念研究方面 ,必须对由远程航天器上传回的激光进行讯号的测量与处理。激光经过长距离的传输后 ,功率大幅下降 ,因此在空间任务概念的考虑上 ,弱光锁相是计划中关键性的技术。由航天器射来的激光 ,经过望远镜聚光后与本地激光进行锁相 ,由本地激光承载及传达太空激光的相位信息。实验中 ,我们使用 2支半导体激光泵浦非平面环形共振腔钇镏石激光 (Diodelaserpumpednon -planarringcavityNd :YAGlaser) ,分别代表远程的弱光及代表本地的强光 ,建立弱光锁相环路系统 (weak -lightphase -lockedloopsystem)。以中性光强度滤光器 (ND -filter;neutraldensityfilter)减弱光讯号来仿真远程激光传来的弱光。在相位探测部分使用均衡探测法 ,消除激光强度噪声 ,以提高讯噪比。同时配合适当的环路滤波器 ,控制激光频率 ,提高锁相的能力。对 2nW的弱光与 2mW的强光可长时间锁相 ,其均方根相位误差为 57mrad。 2 0 0pW的弱光与 2 0 0 μW的强光锁相时间可达 2h以上 ,其相位误差为 2 0 0mrad。 2 0pW的弱光与 2 0 0 μW的强光锁相时间亦可达 2h以上 ,其相位误差为 1 60mrad。最后 ,我们对 2pW的弱光与 2 0 0 μW的强光锁相 ,  相似文献   

纳米计量学的基础技术组件   总被引：2，自引：0，他引：2  

叶贤基 《天文研究与技术》2002,(3):101-116

为了满足ASTROD激光宇航动力学任务慨念计划的高精度要求 ,以及实现新质量标准 ,我们开始进行次纳米激光测长与纳米定位控制的研究。本文将回顾我们在清华大学与工研院测量中心的研究成果 ,介绍如何利用外差式激光干涉仪、挠性微动台与压电陶瓷 ,进行次纳米激光测长与纳米定位控制。此研究成果将做为ASTROD计划中 ,无拖曳航天技术的研发基础。之后讨论如何将纳米定位控制系统与扫描穿隧显微镜进行整合 ,完成计量型扫描穿隧显微镜 ,进一步将微结构的测量尺寸直接追溯至长度标准。  相似文献   

A land surface model (IAP94) for climate studies Part II: Implementation and preliminary results of coupled model with IAP GCM     

Dai Yongjiu  Xue Feng  Zeng Qingcun 《大气科学进展》1998,15(1):47-62

The Institute of Atmospheric Physics Land Surface Model (IAP94) has been incorporated into the IAP two-level atmospheric general circulation model (IAP GCM). Global and regional climatology averaged over the last 25 years of 100 year integrations from the IAP GCM with and without IAP94 (“bucket” scheme) is compared. The simulated results are also compared with the reanalysis data. Major findings are:(1) The IAP GCM simulation without IAP94 has extensive regions of warmer than observed surface air tempera?tures, while the simulation with IAP94 very much improves the surface air temperature.(2) The IAP GCM simulation with IAP94 gives improvement of the simulated precipitation pattern and intensity, especially the precipitation of East Asian summer monsoon and its intraseasonal migration of the rainbelts.(3) In five selected typical regions, for most of the surface variables such as surface air temperature, precipitation, precipitation minus evaporation, net radiation, latent heat flux and sensible heat flux, the IAP GCM with IAP94 pro?vides better simulations.  相似文献   

GPS卫星的激光测距和应用研究   总被引：2，自引：0，他引：2  

许华冠 《天文学进展》1998,16(4):251-259

简述了SLR和GPS跟踪技术的发展概况。详细介绍了近几年来对GPS－35、36卫星的激光测距进展和应用研究的情况。给出了残差分析的初步结果,并指出了目前GPS卫星的稀少的激光测距资料对卫星精密定轨和站坐标的解算是有价值的。同时,也简单地评述了GPS卫星的微波和激光跟踪技术各自的优势和弱点．建议联合利用GPS-35、36卫星的SLR和GPS观测资料来开展有关的应用研究。最后,对今后的应用研究工作提出了建议．  相似文献   

Sulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS   总被引：4，自引：0，他引：4  

Paul R. Craddock  Olivier J. Rouxel  Lary A. Ball  Wolfgang Bach   《Chemical Geology》2008,253(3-4):102-113

We have developed a technique for the accurate and precise determination of ³⁴S/³²S isotope ratios (δ³⁴S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O₂⁺. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical.  相似文献   

A continuous/discontinuous Galerkin framework for modeling coupled subsurface and surface water flow     

Clint Dawson 《Computational Geosciences》2008,12(4):451-472

We consider conjunctive surface-subsurface flow modeling, where surface water flow is described by the shallow water equations and ground water flow by Richards’ equation for the vadose zone. Coupling between the models is based on the continuity of flux and water pressure. Numerical approximation of the coupled model using the framework of discontinuous Galerkin (DG) methods is formulated. In the subsurface, the local discontinuous Galerkin (LDG) method is used to approximate ground water velocity and hydraulic head; a DG method is also used to approximate surface water velocity and elevation. This approach allows for a weak coupling of the models and the use of different approximating spaces and/or meshes within each regime. A simplified LDG method based on continuous approximations to water head is also described. Numerical results that investigate physical and numerical aspects of surface–subsurface flow modeling are presented. This work was supported by National Science Foundation grant DMS-0411413.  相似文献   

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances   总被引：2，自引：2，他引：0  

Alain Cocherie  Michle Robert 《Gondwana Research》2008,14(4):597

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.  相似文献